Solar Photovoltaic Powered On-Site Ammonia Production for Nitrogen Fertilization

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Ammonia synthesis is the most important step for nitrogen-fertilizer production and consumes approximately 1% of the world’s energy production and energy-related greenhouse gas emissions. In addition to the concomitant emissions caused by ammonia and nitrogen fertilizer synthesis, centrally produced fertilizer that must be distributed to farms also harms the environment because of the embodied energy of transportation. An environmentally-optimal nitrogen fertilizer system would be distributed on farms themselves using only renewable inputs. Recent developments in solar photovoltaic technology and subsystems for ammonia production have made non-organic on-site ammonia production physically possible. This study provides a technical evaluation of the process for on-site nitrogen-fertilization of corn using solar photovoltaic electricity as the energy input. The system consists of a water electrolysis system to generate hydrogen and a membrane system to generate nitrogen needed as material inputs. Total power consumption for syngas preparation to generate a unit of ammonia is calculated. System total energy consumption is calculated while compensating syngas preparation with heat recovery. Five case-study locations are evaluated to determine their suggested nitrogen fertilizer addition (N-rate) for corn growth and the energy consumption for suggested N-rate is calculated. The System Advisor Model (SAM) is then used to simulate the PV system output for those five locations. Finally, the PV land use required as a fraction of the corn field area is determined. The results indicate that because PV is so much more efficient at solar energy conversion than organic methods, even the worst case evaluated in Indiana requires less than 1% of the corn field converted to a PV system to provide enough energy to generate sufficient amounts of ammonia for fertilizer for the remaining corn. The system was modeled to provide ammonia to fertilize for corn fields larger than 1079 acres with the worst soil conditions, the area of which applies to more than half of cropland in the U.S. in 2011. As the finiteness and emissions of fossil fuel production of nitrogen become more important, this renewable system should become economical and future investigations into its overall viability are warranted.

▼Pearce publications

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Agrivoltaics · Energy Conservation · Energy Policy · Floatovoltaivs · Industrial Symbiosis · Life Cycle Analysis · Materials Science · Medical · Open Source · Photovoltaic Systems · Resilient Food · Solar Cells · Sustainable Development · Sustainability Education · Water

• Environmental nitrogen fertilizer system is distributed using renewable energy.
• Energy consumption to generate N using water electrolyzer has been calculated.
• Energy consumption to provide N fertilizer for unit corn field has been calculated.
• Land required for photovoltaic fertilizer production for corn has been simulated.
• Results show <1% of the corn field converted to a PV system for N-fertilizer energy.

The Western Innovation for Renewable Energy (WIRED) system is currently under construction to test out new open source methods to reduce PV systems costs and enable novel forms of agrivoltaics including the world's first agrivoltaic agrotunnel.

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  The Agrivoltaic Potential of Canada
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  Social acceptance of agrivoltaics in Canada: Insights on public perceptions across technologies and provinces from a nationwide survey
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  Net Zero Agrivoltaic Arrays for Agrotunnel Vertical Growing Systems: Energy Analysis and System Sizing
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  Regenerative Agrivoltaics: Integrating Photovoltaics and Regenerative Agriculture for Sustainable Food and Energy Systems
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  Agrivoltaics as a systems innovation: multi-dimensional benefits from global studies across climate, agriculture, energy, and ecosystems
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  Creating just agrivoltaic transitions for large-scale solar: a comparative multi criteria analysis
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  The potential of agrivoltaic systems to meet energy demand of data centers in the United States
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  Some like it hot, some like it partially shaded: The effect of semi-transparent solar photovoltaic modules on the growth metrics of greenhouse cultivated spicy peppers
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  Integration of semi-transparent photovoltaic modules and heat pumps into agrivoltaic tomato greenhouses: Energy, economic, and environmental savings
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  Strawberry agrivoltaics in Canada: Comparing uniform thin film and non-uniform crystalline silicon semi-transparent solar photovoltaic modules in controlled environment agriculture
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  Climate-Resilient Crop Production Under Agrivoltaics: Experimental Evaluation of Amaranth Production With Semi-Transparent Photovoltaic Modules in Canada Under Changing Climates
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  Is Non-Thermal Plasma Treatment of Commodity Lettuce Seeds Worth It? Economic Impacts and Yield of Lettuce in Indoor Vertical Farming Testing Dry Air, Wet Air, N2 and O2 Plasmas
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  Lighting Energy and Revenue Analysis in an Agrivoltaic Agrotunnel for Lettuce and Swiss Chard Production
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  Full Heads or Cut and Come Again? Economic Analysis of Leafy Green Cultivation in Solar-Powered Indoor Vertical Farms
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  Heat Stress Tolerance in Organic Romaine Lettuce Using Crystalline Silicon and Red, Blue & Green-Colored Thin Film Agrivoltaic Systems
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  Agrivoltaic Lettuce Production Under Future Climates: A Sustainable Strategy for Optimizing Food and Energy Yields
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  Effects of Thin-Film and Wafer-Based Photovoltaic Module Transparency and Spectral Properties on Microclimate and Turnip Yield in Agrivoltaic Systems
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  Photosynthetically active radiation complexities in agrivoltaic policy mandates: Insights from controlled environment yields under semitransparent photovoltaics
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  Should Agrivoltaics Ever Be Decommissioned? How Agrivoltaics Bolster Farm Climate Adaptation Even When Unpowered
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  Transparency effects in agrivoltaics lettuce cultivation using uniform/non-uniform semitransparent photovoltaic modules in controlled environments
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  Impacts of Type of Partial Transparency on Strawberry Agrivoltaics: Uniform Illumination Thin Film Cadmium-Telluride and Non-uniform Crystalline Silicon Solar Photovoltaic Modules
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  Additional value of non-electricity generating services (co-benefits) provided by non-conventional dual use solar photovoltaic systems: A PRISMA review
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  An open-source spectral measurement platform for plant reflectance and material identification
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  Open-Source Photosynthetically Active Radiation Sensor for Enhanced Agricultural and Agrivoltaics Monitoring
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  Effects of Spectral Ranges on Growth and Yield in Vertical Hydroponic–Aeroponic Hybrid Grow Systems for Radishes and Turnips
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  Financial Analysis of Agrivoltaic Sheep: Breeding and Auction Lamb Business Models
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  Experimental impacts of transparency on strawberry agrivoltaics using thin film photovoltaic modules under low light conditions
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  Open-Source Indoor Horizontal Grow Structure Designs
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  Greenhouse applications of solar photovoltaic driven heat pumps in northern environments
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  Solar Energy Modelling and Proposed Crops for Different Types of Agrivoltaics Systems
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  Maximizing Biomass with Agrivoltaics: Potential and Policy in Saskatchewan Canada
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  Energy Policy for Agrivoltaics in Alberta Canada
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  Agrivoltaics in Ontario Canada: Promise and Policy
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  Energy Modeling and Techno-Economic Feasibility Analysis of Greenhouses for Tomato Cultivation Utilizing the Waste Heat of Cryptocurrency Miners
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  Advancing Agrivoltaics within the U.S. Legal Framework: A Multidimensional Assessment of Barriers & Opportunities
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  Low cost climate station for smart agriculture applications with photovoltaic energy and wireless communication
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  Design and Implementation of 3-D Printed Radiation Shields for Environmental Sensors
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  Design of a low-cost mobile multispectral albedometer with geopositioning and absolute orientation
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  Parametric Open Source Cold-Frame Agrivoltaic Systems
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  Impacts of Location on Designs and Economics of DIY Low-Cost Fixed-Tilt Open Source Wood Solar Photovoltaic Racking
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  Open-Source Design and Economics of Manual Variable-Tilt Angle DIY Wood-Based Solar Photovoltaic Racking System
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  Solar photovoltaic wood racking mechanical design for trellis-based agrivoltaics
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  Open-Source Vertical Swinging Wood-Based Solar Photovoltaic Racking Systems
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  Vertical Free-Swinging Photovoltaic Racking Energy Modelling: A Novel Approach to Agrivoltaics
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  Optimal inverter and wire selection for solar photovoltaic fencing applications
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  The potential for fencing to be used as low-cost solar photovoltaic racking
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  Do agrivoltaics improve public support for solar? A survey on perceptions, preferences, and priorities
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  Greener Sheep: Life Cycle Analysis of Integrated Sheep Agrivoltatic Systems
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  Life cycle assessment of pasture-based agrivoltaic systems: Emissions and energy use of integrated rabbit production
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  Conceptual Design and Rationale for a New Agrivoltaics Concept: Pastured-Raised Rabbits and Solar Farming
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  Integrating solar energy with agriculture: Industry perspectives on the market, community, and socio-political dimensions of agrivoltaics
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  A First Investigation of Agriculture Sector Perspectives on the Opportunities and Barriers for Agrivoltaics
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  Open-Source Script for Design and 3D Printing of Porous Structures for Soil Science
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  Agrivoltaic potential on grape farms in India
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  Aquavoltaics: Synergies for dual use of water area for solar photovoltaic electricity generation and aquaculture
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  The potential of agrivoltaic systems
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  Solar Photovoltaic Powered On-Site Ammonia Production for Nitrogen Fertilization
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  Open-Source Photometric System for Enzymatic Nitrate Quantification
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  Open-source manufacturing of polypropylene replacements for peat cups in vertical farming: improvements in life cycle embodied energy, greenhouse gas emissions, labor and operational costs
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  Agrivoltaics Canada

• Coal with Carbon Capture and Sequestration is not as Land Use Efficient as Solar Photovoltaic Technology for Climate Neutral Electricity Production
• Dual use of land for PV farms and agriculture literature review
• sheep
• Israeli white plastic reflectors

• A Farmer's Guide to Going Solar (NREL)
• German guidelines: https://www.ise.fraunhofer.de/content/dam/ise/en/documents/publications/studies/APV-Guideline.pdf
• 2021 review
• Miskin, C.K., Li, Y., Perna, A., Ellis, R.G., Grubbs, E.K., Bermel, P. and Agrawal, R., 2019. Sustainable co-production of food and solar power to relax land-use constraints. Nature Sustainability, 2(10), pp.972-980.
• Retrofitting solar parks for agrivoltaics
• Shading PV
• Alexis' talk at American Solar Grazing Association2021

1. Solar Sheep, Alberta (https://www.solarsheep.ca/)
2. Sun Cycle Farms, Alberta (https://suncyclefarms.com/)
3. Golden Leaf Agrivoltaics, Ontario (https://goldenleafagrivoltaics.ca/)
4. The Lara Cost Farm, Ontario (https://thelaracosta.com/)
5. Arnprior Solar, Ontario (https://www.edf-re.com/project/arnprior-solar/)
6. Lewis Land & Stock, Ontario (https://solargrazing.org/asga-call-29-don-lewis-from-lewis-land-stock-of-ontario-canada/)
7. Nanticoke Solar, Ontario (https://www.opg.com/stories/hundreds-of-grazing-sheep-helping-to-keep-opgs-nanticoke-solar-facility-in-trim-shape/)
8. Western University’s Western Innovation for Renewable Energy Deployment (WIRED) (https://www.appropedia.org/Western_Innovation_for_Renewable_Energy_Deployment_(WIRED))
9. Orchard, Middlesex, Ontario
10. Solar Grazing Map https://solargrazing.org/map/

• Photovoltaic Nitrogen-fixation and organic farming literature review
• Open-Source Photometric System for Enzymatic Nitrate Quantification