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Evaluation of plasma-reaction-driving capability in dielectric barrier discharge systems: Insights from CH4 splitting

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Calculated discharge parameters, PED value, and performance of plasma-assisted CH4 splitting with different (A–C) inner electrode materials and (D–F) lengths of outer electrode. (G) Diagram and (H) photograph of the active microdischarge zone on the DBD reactor.
Publication data
Type Research
Title Evaluation of plasma-reaction-driving capability in dielectric barrier discharge systems: Insights from CH4 splitting
Description
Authors
Year 2026
Language English (en)
License CC-BY-SA-4.0
Cite as Zou N, Pearce JM, Bassi A, Boutilier MSH, Zheng Y. Evaluation of plasma-reaction-driving capability in dielectric barrier discharge systems: Insights from CH4 splitting. AIChE Journal. 2026;e70565. https://doi.org/10.1002/aic.70565 OA Academia.edu
Project data
Type
Authors Nan Zou
Joshua M. Pearce
Amarjeet Bassi
Michael S. H. Boutilier
Ying Zheng
Location London, ON, Canada
Status Designed
Modelled
Prototyped
Verified
Verified by FAST
Years 2026
Uses hydrogen
OKH Manifest Download

Dielectric barrier discharge (DBD) plasma systems are promising routes for CH4 splitting to COx-free hydrogen, but their optimization has historically been hindered by the lack of a universal descriptor linking electrical input with chemical output. Here, we propose the plasma effective driving factor (PED) as a physics-informed engineering descriptor for evaluating plasma-reaction-driving capability in DBD reactors. PED integrates three coupled aspects of plasma activation: electric-field-driven electron acceleration, electron–molecule collision efficiency, and reactor-scale participation of active microdischarges. Using CH4 splitting as the primary reaction system, we show that PED captures plasma discharge and performance variations not consistently resolved by conventional electrical parameters. Extension to published DBD systems suggests the potential of PED for comparative analysis beyond the present CH4 splitting system. Overall, PED provides a practical engineering framework for relating discharge-state variation to chemical reaction response and offers a comparative basis for evaluating plasma-reaction-driving capability across different DBD conditions.

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