Solar Pura render.jpeg
Page data
Keywords water purification, solar energy
SDGs Sustainable Development Goals SDG06 Clean water and sanitation
SDG07 Affordable and clean energy
Authors Jaran Ellermeyer
Eric Blazek
Lonny Grafman
Published 2007
License CC BY-SA 3.0
Derivatives Solar-Destillierapparat
Language English (en)
Page views 78,910

Solar distillation is the use of solar energy to evaporate water and collect its condensate within the same closed system. Unlike other forms of water purification it can turn salt or brackish water into fresh drinking water (i.e. desalination). The structure that houses the process is known as a solar still and although the size, dimensions, materials, and configuration are varied, all rely on the simple procedure wherein an influent solution enters the system and the more volatile solvents leave in the effluent leaving behind the salty solute behind.[1]

Solar distillation differs from other forms of desalination that are more energy-intensive, such as methods such as reverse osmosis, or simply boiling water due to its use of free energy.[2][3] A very common and, by far, the largest example of solar distillation is the natural water cycle that the Earth experiences.

Solar stills are a type of appropriate technology used to distill water using the power of the sun. In any solar still, the basic layout is a collection device to capture rainwater. In most cases the collector is covered by a sheet of glass or transparent plastic, which allows solar radiation to pass through but not to escape. Water evaporated by the radiant solar heat then condenses on the cooler cover material. The condensed water is free from impurities, such as salts and heavy metals, as well as microbiological organisms, that might have been present in the intake water. The end result is a supply of fresh, clean water. Solar stills can efficiently produce drinking water from ditch water or cistern water, especially high-efficiency multiple effect humidification designs, which separate the evaporator(s) and condenser(s).

Projects on Appropedia[edit | edit source]

History[edit | edit source]

Carlos Wilson, Swedish Engineer[4]
Early Solar Still by Della Porta[4].

The earliest onset of solar energy use to desalinate water is widely accredited to Aristotle during the fourth century B.C.E.[4][5][6] [7] Earlier attributions reference the Bible & Moses' use of a piece of wood to remove the "bitterness" from water (Exodus 15:25, English Standard Version). Solar stills have been used for hundreds of years. The earliest known examples date to 1551 when Arab alchemists used such stills. The first documented account of solar distillation use for desalination was by Giovani Batista Della Porta in 1958.[4]However, no solar distillation publication of any repute leaves out the Father of solar distillation, Carlos Wilson, the creator of the first modern sun-powered desalination plant; a massive solar still plant which was used to supply fresh water to a mining community, built in Las Salinas (The Salts), Chile in 1872.[4][7][8] [9] [10] [11]This desalination plant, "can be considered to be the first industrial installation for exploitation of solar energy[11]."

The Las Salinas plant was envisioned to take advantage of the nearby saltpeter mining effluent to supply the miners and their families freshwater [4]. The facility was quite large for its time and now:

"The plant was constructed of wood and timber framework covered with one sheet of glass. It consisted of 64 bays having a total surface area of 4450 m2 and a total land surface area of 7896 m2. It produced 22.70 m3 of fresh water per day. The plant was in operation for about 40 years until the mines were exhausted[4]."

Interest in solar distillation wavered for some time, until historical events prompted further research and development. World War II was a great catalyst for the Massachusetts Institute of Technology to develop appropriate solar stills for use in more remote areas of the world during emergencies. These small solar stills were made to float on and collect saltwater to desalt as they floated alongside life-boats and rafts[4]. More significant studies into solar distillation were carried out by the Office of Saline Water, a sector the US government, in 1952. Many experiments were performed on different conceptualizations of the solar still, including multiple-effect basins and the application of condensers[4]. This trend ended near the early 70's with the advent of more lucrative desalination techniques like the aforementioned reverse osmosis or multi-stage flash, a technique that involves a series of stages where evaporation relies on lowering the pressure of each stage to lower the boiling or "flashing" point of the water [12][13]

Today, renewed enthusiasm for solar distillation comes from individuals, communities, and organizations seeking an appropriate technology that is cheap, simple, and conceivable in rural settings.[14] For this reason, hundreds of solar still plants and thousands of individual solar stills have been built around the world.

Types[edit | edit source]

Schematic of a box-type solar still
Drawing of Emergency Solar Still
Simple Single-Effect Basin Still[15]

From most sophisticated to least so, their three basic configurations are:

  • box-like
  • cone-shaped
  • pit type

The fundamental aspects of a solar still have gone unchanged since ancient times, the simplicity of the design is one of the solar still's chief benefits. However, there are many variations on the theme of the typical single slope/basin still and these can fall into one of two categories, active or passive. These labels classify the still by the method it uses to acquire the energy to drive the evaporation of the water. Passive solar stills are, of course, more conventional and have been the only ones discussed up to this point. Active stills, however, can obtain "waste" heat from a myriad of sources. A good insulator is necessary to reduce thermal losses and prolong the evaporation process even into the night.[16][17] Insulation that could be used include things like styrofoam with a polypropylene cover, or wool (which, can retain some of its insulation even when wet).[18][19]

Passive solar stills[edit | edit source]

Conventional solar stills rely solely on the sun to distill water, however their complexity could still reach that of active stills, if not other more intricate desalination methods. Passive stills, then, vary widely due to this one constraint and can be further organized into sub-classes. Some common types of passive solar stills include[13]:

  • Single-effect
  • Multi-effect
  • Basin
  • Double Slope
  • Wick
  • Multi-wick
  • Diffusion
  • Greenhouse
  • Single-effect stills

Single-effect stills are the simplest and most common, since only one interface is necessary to convey the energy and collect the condensate. An example of a crucial design challenge in all solar stills is keeping the distiller airtight. If not airtight, efficiency drops severely [7].Often a shallow trough is used, painted black, and flooded. A slanted pane of glass covering, allowing condensed water vapor to slide down into an output channel. Expect 1 gallon per day per square meter of glass. Another approach is molded plastic, e.g. the Watercone (see below). This has the advantage that it is can be more easily made airtight, and mass production should make it affordable.

  • Multi-effect stills

Multi-effect stills require double the effort in regards to ensuring tight seals, and could be more to difficult to clean, but they can raise the production of freshwater significantly.[20] The way, by which, the water is stored for its time in the liquid phase can also contrast.

  • Basin-type stills

Basin-type stills contain the water in an impervious material that is a component of the entire enclosure and are the most ubiqutious.

  • Wick stills

Wick stills use cloth-like materials that use capillary action to propagate the water through the system. When efficiency and effectiveness are key, wick stills out-produce basin stills due to the greater surface area of evaporation, lower energy cost to heat the water, and ability to create a much larger effective area for solar radiation to transfer energy into the water.[21]

  • Multi-wick stills

Multi-wick stills obviously play off of typical wick stills and much like the multi-effect premise from above, they greatly increase the productivity for increasing the influenced surface area exponentially.[22]

  • Diffusion-type stills

Diffusion-type stills run with the ideas introduced by the mutli-effect & -wick stills and a further advancement to both. Perhaps, Tanaka & Nakatake best explain the design behind these efficient stills, "which consist of a series of closely spaced parallel partitions in contact with saline-soaked wicks, have great potential because of their high productivity and simplicity.[23]"

One more variation on solar stills is caught in the middle of the two predetermined categories of passive and active, and could perhaps be labeled "neutral". Seawater Greenhouses (i.e. Kiva's straw bale greenhouse) marry the concept of solar distillation with the more prominent greenhouse premise. They are neutral because the energy that goes in to create the freshwater, even if active, pays off by the freshwater's invaluable quality to grow the plants that promote the evaporative cooling of the air inside, which, ultimately carries the moisture.[24]

Seawater Greenhouse[24]

Active solar stills[edit | edit source]

These distillers use additional heat sources to promote existing thermal processes.[25] The foundation of the design of these desalters has already been lain in the above section, so the sources involved with this branch of solar stills will be discussed with brevity:

  • CPCs (Compound Parabolic [Solar] Concentrators)
  • Flat Plate Collectors[26]
  • Solar Heater[13]*Novel Waste Heat (i.e. vehicle radiator)[27]

Active stills add another element of complexity to the not so complex base design, but once again this alteration can promote faster, and larger quantities of freshwater generation.

Theory[edit | edit source]

The immediate abstraction to make is to the Earth's natural system, but as it was aforementioned, this is unjustified but only if one believes that the water cycle on Earth is a non-complex concept. In "Understanding Solar Stills" it is said,

"It takes a lot of energy for water to vaporize. While a certain amount of energy is needed to raise the temperature of a kilogram of water from 0 to 100 Celcius (C), it takes five and one-half times that much to chnage it from water at 100°C to water vapor at 100°C. Practically all this energy, however, is given back when the water vapor condenses... This is the way we get fresh water in the clouds from the oceans, by solar distillation. All the fresh water on earth has been solar distilled.[7]"

The journey for a water molecule from the aqueous to gaseous phase is more difficult to acquiesce than the eloquent writing above. As we will see a tremendous factor will be the difference in temperature between the surface water and that of the interface, be it glass or plastic. Some relevant equations include:[28]

Solar Still Eqns.jpg

Eqn. (1) from the above describes the instantaneous thermal efficiency in relation to the evaporative heat transfer rate from the water surface to the glass cover the solar radiation intensity. Eqn.(2) represents the evaporative heat transfer rate from Eqn. (1) and its relationship to product of the convective heat transfer coefficient from the water surface to glass difference between the partial vapor pressure of water and gas. Eqn.(3) is the equation for determining the monthly output of distillate. Eqn.(4) was developed to describe the pay back period, np as a function of the Unacost, or the uniform end-of-year annual amount with P being the initial cost and i the interest rate.

Construction[edit | edit source]

Many different methods exist to build solar stills, the most rudimentary involves digging a hole and more the more complex coming off of a manufacturing line.

Materials[edit | edit source]

Common Materials List[7]:

  • insulation (usually under the basin)
  • sealants
  • piping and valves
  • facilities for storage
  • a reflector to concentrate sunlight
  • structural components
  • wicking fabrics
  • blackened wood
  • black jute
  • black polyethylene

Locally available materials would always be preferred but many things, such as the sealants, might be necessary to find from foreign vendors[6]. A very practical and thorough tutorial on how to build a small-scale solar still is available here: "A Small Homemade Solar Still"

Compound parabolic concentrators[edit | edit source]

As regional shortages of fresh water become more prevalent, solar distillation using a single-effect basin holds promise as a method to bring low-cost, clean, and ecologically-responsible water to remote area dwellers. Compound parabolic concentrators (CPCs) can be used to direct more light onto the still increasing the throughput and efficiency of these passive solar devices. A computer program has been developed that uses the properties of materials and the solar energy characteristics of the site to calculate the increase in output of water due to reflectors of different height. For reflector 2.5 times the width of the still, the output per unit area per day roughly triples with only ~10% increase in cost and moderate maintenance (weekly tilts), indicating that CPCs have a significant economic advantage in producing solar distilled water. For full paper

Operation and maintenance[edit | edit source]

Since one of the main goals of solar distillation is to provide a clean source of water, proper disinfection after construction is crucial. Some less intensive methods of cleaning could be use of soap or laundry detergent[7]. A glass cover is more advantageous with respect to maintenance than a plastic cover, due to the electrostatic properties of plastic that can make it a beacon for detritus[14]. The brine left over after thorough distillation can be harvested for sea salt, as it is now a valuable commodity in its own right.[29]

Applications[edit | edit source]

Generally, solar stills are used in areas where piped or well water is impractical to obtain. Such areas include remote locations or locations where frequent power outages make pumps undependable. In such areas, solar stills can provide an alternate source of clean water. A major use of small solar stills is in developing countries where the technology to effectively distill large quantities of water on a commercial scale has not yet arrived. The drawback is that each individual still produces a relatively small amount of clean water.

Another application for solar stills is for outdoors back-country survival. Simple solar stills can be created by making use of basic camping gear and materials available in the natural environment. Stills for survival purposes would generally be of the relatively unsophisticated pit type, since they are the simplest to produce. One can extract moisture from the ground, but locally available moisture can be supplemented with water added inside or along the edges of the still. Where no water sources are readily available, urine or shredded vegetation can be used inside the pit. Whilst makeshift solar stills often do not provide enough water for long-term survival, they can prevent dehydration for short periods of time.

Real world[edit | edit source]

In "Social aspects of a solar-powered desalination unit for remote Australian communities" Warner & Schafer argue that many journals, researchers and others like them rely too much on the technical aspects of solar distillation to prove its worth, "in order to be socially sustainable, such technologies must:

  • be accepted by the community,
  • meet their water needs, and
  • be within their capacity to operate and maintain.[30]" The situation that exists today has not changed much from even 50 years ago. Energy and cost intensive technologies still champion over desalination in the modern world.[31]

For this reason, many developing countries and communities, on large and small-scale levels resort to the status quo, when more appropriate resorts exist.[32]

Videos[edit | edit source]

Fresh Water with 3D Printed Water Distiller

See also[edit | edit source]

References[edit | edit source]

  1. (2008). Desalination, a national perspective. National Research Council of the National Academies.
  2. Abu-Arabi, M. (2007). Status and prospects for solar desalination in the MENA region. Solar Desalination for the 21 st Century, 163-178.
  3. Paton, C., & Davies, P. (2006). The seawater greenhouse cooling, fresh water and fresh produce from seawater. In The 2nd International Conference on Water Resources in Arid Environments, Riyadh.
  4. 4.0 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 Delyannis, E. (2003). Historic background of desalination and renewable energies. Solar Energy, 75(5), 357-366.
  5. Tiwari, G. N., Singh, H. N., & Tripathi, R. (2003). Present status of solar distillation. Solar Energy, 75(5), 367-373.
  6. 6.0 6.1 Velmurugan, V., & Srithar, K. (2011). Performance analysis of solar stills based on various factors affecting the productivity—A review. Renewable and Sustainable Energy Reviews, 15(2), 1294-1304.
  7. 7.0 7.1 7.2 7.3 7.4 7.5 Gordes, J., & McCracken, H. (1985). Understanding Solar Stills. Volunteers in Technical Assistance (VITA).
  8. Al-Hayeka, I., & Badran, O. O. (2004). The effect of using different designs of solar stills on water distillation. Desalination, 169(2), 121-127.
  9. Goosen, M. F., Sablani, S. S., Shayya, W. H., Paton, C., & Al-Hinai, H. (2000). Thermodynamic and economic considerations in solar desalination. Desalination, 129(1), 63-89.
  10. Bouchekima, B. (2003). A small solar desalination plant for the production of drinking water in remote arid areas of southern Algeria. Desalination, 159(2), 197-204.
  11. 11.0 11.1 Hirschmann, J. R. (1975). Solar distillation in Chile. Desalination, 17(1), 31-67.
  12. El-Dessouky, H. T., Ettouney, H. M., & Al-Roumi, Y. (1999). Multi-stage flash desalination: present and future outlook. Chemical Engineering Journal, 73(2), 173-190.
  13. 13.0 13.1 13.2 Fath, H. E. (1998). Solar distillation: a promising alternative for water provision with free energy, simple technology and a clean environment. Desalination, 116(1), 45-56.
  14. 14.0 14.1 Eibling, J. A., Talbert, S. G., & Löf, G. O. G. (1971). Solar stills for community use—digest of technology. Solar energy, 13(2), 263-276.
  15. Ettouney, H., & Rizzuti, L. (2007). SOLAR DESALINATION: A CHALLENGE FOR SUSTAINABLE FRESH WATER IN THE 21 ST CENTURY. Solar Desalination for the 21 st Century, 1-18.
  16. Löf, G. O. (1961). Fundamental problems in solar distillation. Proceedings of the National Academy of Sciences of the United States of America, 47(8), 1279.
  17. Goosen, M. F., Sablani, S. S., Shayya, W. H., Paton, C., & Al-Hinai, H. (2000). Thermodynamic and economic considerations in solar desalination. Desalination, 129(1), 63-89.
  18. Ihalawela, P. H. C. A., & Careem, M. A. (2007). A cheap automatic solar water distiller. In Proceedings of the technical sessions (Vol. 23, pp. 41-45).
  19. BACHA, H., Maalej, A. Y., & DHIA, H. B. (2007). A Methodology to Predict Operation of a Solar Powered Desalination Unit. Solar Desalination for the 21 st Century, 69-82.
  20. Blanco, J., & Alarcón, D. (2007). The PSA experience on solar desalination: technology development and research activities. Solar Desalination for the 21 st Century, 195-206.
  21. Noble, Neil (2012). Solar Distillation. Retrieved from http://web.archive.org/web/20140608080946/http://practicalaction.org:80/solar-distillation-1
  22. Velmurugan, V., & Srithar, K. (2011). Performance analysis of solar stills based on various factors affecting the productivity—A review. Renewable and Sustainable Energy Reviews, 15(2), 1294-1304.
  23. Tanaka, H., & Nakatake, Y. (2007). Outdoor experiments of a vertical diffusion solar still coupled with a flat plate reflector. Desalination, 214(1), 70-82.
  24. 24.0 24.1 Paton, C., & Davies, P. (2006). The seawater greenhouse cooling, fresh water and fresh produce from seawater. In The 2nd International Conference on Water Resources in Arid Environments, Riyadh.
  25. AYBAR, H. (2007). A review of desalination by solar still. Solar Desalination for the 21 st Century, 207-214.
  26. Kabeel, A. E., & El-Agouz, S. A. (2011). Review of researches and developments on solar stills. Desalination, 276(1), 1-12.
  27. Mandaville, J. (1972). Some Experiments with Solar Ground Stills in Eastern Arabia. Geographical Journal, 64-66.
  28. Medugu, D. W., & Ndatuwong, L. G. (2009). Theoretical analysis of water distillation using solar still. International Journal of Physical Sciences, 4(11), 705-712.
  29. KOPSCH, O. (2007). SOLAR STILLS: 10 YEARS OF PRACTICAL EXPERIENCE IN COMMERCIALISING SOLAR STILLS WORLDWIDE. Solar Desalination for the 21 st Century, 239-246.
  30. Werner, M., & Schäfer, A. I. (2007). Social aspects of a solar-powered desalination unit for remote Australian communities. Desalination, 203(1), 375-393.
  31. Chaibi, M. T. (2000). An overview of solar desalination for domestic and agriculture water needs in remote arid areas. Desalination, 127(2), 119-133.
  32. Bloemer, J. W., Eibling, J. A., Irwin, J. R., & Löf, G. O. (1965). A practical basin-type solar still. Solar Energy, 9(4), 197-200.

External links[edit | edit source]