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*Bethany C. Gross, Jayda L. Erkal, Sarah Y. Lockwood, Chengpeng Chen, and Dana M. Spence: [http://pubs.acs.org/doi/abs/10.1021/ac403397r Evaluation of 3D Printing and Its Potential Impact on Biotechnology and the Chemical Sciences], Anal. Chem., 2014, 86 (7), pp 3240–3253, DOI: 10.1021/ac403397r | *Bethany C. Gross, Jayda L. Erkal, Sarah Y. Lockwood, Chengpeng Chen, and Dana M. Spence: [http://pubs.acs.org/doi/abs/10.1021/ac403397r Evaluation of 3D Printing and Its Potential Impact on Biotechnology and the Chemical Sciences], Anal. Chem., 2014, 86 (7), pp 3240–3253, DOI: 10.1021/ac403397r | ||
* | *Philip J. Kitson, Stefan Glatzel, Wei Chen, Chang-Gen Lin, Yu-Fei Song,and Leroy Cronin: [https://www.nature.com/articles/nprot.2016.041.pdf 3D printing of versatile reactionware for chemical synthesis], Nat. Protocols, 2016, 11 (5), 920-936 | ||
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Revision as of 10:57, 10 November 2017
This is a literature review for a study on the chemical resistance of 3D printable polymers. This literature review is initially targeted at liquid chemicals which can "attack" 3D printed polymers. In the future gas and plasma attack can be studied but for now it is out of the scope of this lit review.
Introduction
Chemicals and processes
List of chemicals
The resistance of 3D printable materials at least to the following solvents, acids and solutions is tested:
- Deionized H2O
- Isopropanol
- Acetone
- Hydrochloric acid (HCl), 37%
- Ammonia (NH3), aqueous solution 25%
- Hydrogen peroxide (H2O2), aqueous solution 30%
- Nitric acid (HNO3)
- Phosphoric acid (H3PO4)
- Acetic acid, concentrated
These chemicals are common chemicals used in many laboratories and many semiconductor processing steps, such as in the cleaning of silicon wafers.
Chemical processes
- Resist strip
- RCA1 and RCA2 wafer cleaning processes
3D printing materials and their chemical properties
PLA (Polylactic acid)
One of the most used 3D printing filaments. Various vendors and available in multiple colors. Biodegradable, potentially not very resistant to chemicals.
ABS (Acrylonitrile butadiene styrene)
Co-polyesters
Commercial 3D printing filaments: Inova Co-Polyester, ColorFabb nGen
PETG
PP (Polypropylene)
Resistant to various laboratory chemicals. Quite resistant to acids and bases. Widely used in clean rooms. Is susceptible to oxidation for example peroxides, as it is just a hydrocarbon.
PC (Polycarbonate)
PETT
Taulman T-glase is made of PETT.
FEP
Should be in the sweet spot of fluoropolymers. Low enough melting point to be printable but chemically very durable. According to some data should be resistant to nearly all room temperature liquid chemiclas used in clean rooms.
PEI
Ultem(R) is a commercial plastic which mainly consists of PEI.
Nylon
Taulman Alloy 910 is apparently Nylon-based.
PETG
Polyethylene terephthalate modified with glycol.
Organic polymers
General level discussion of organic polymers .Focus here in differences of organic polymers, their production, etc
Fluoro polymers
Contrast these guys to organics
Sources
Books
- Schreirs, J. Modern fluoropolymers. Scheirs, J., Ed (1997): 32.
- Moiseev, Yu V., and Gennadiĭ Efremovich Zaikov. Chemical resistance of polymers in aggressive media. Springer Science & Business Media, 1987.
- Seymour R.B., Carraher C.E. (1984) Chemical Resistance of Polymers. In: Structure—Property Relationships in Polymers. Springer, Boston, MA.
Chemical resistance charts
- Curbell Plastics
- Thermo Scientific Nalgene Products, Cornell University Sevier lab
- Ensinger Plastics
- Sirmax
Journal Articles
- Bethany C. Gross, Jayda L. Erkal, Sarah Y. Lockwood, Chengpeng Chen, and Dana M. Spence: Evaluation of 3D Printing and Its Potential Impact on Biotechnology and the Chemical Sciences, Anal. Chem., 2014, 86 (7), pp 3240–3253, DOI: 10.1021/ac403397r
- Philip J. Kitson, Stefan Glatzel, Wei Chen, Chang-Gen Lin, Yu-Fei Song,and Leroy Cronin: 3D printing of versatile reactionware for chemical synthesis, Nat. Protocols, 2016, 11 (5), 920-936
Searches
Google:
- Chemical resistance of 3D printing materials
- 3D printing filament chemical resistance
- Chemical resistance of polymers
- Chemically resistant 3D printing material
- Chemically resistant 3D printing filament
Scholar:
- Chemical resistance of 3D printing materials
- Fused filament fabrication materials resistance
- Chemical resistance of polymers