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Figures of Merit for GaN substrates

Bulk Type Property Units Characterization Method Industry range Goal Reference/hyperlink
GaN freestanding substrate Bandgap(300K)
eV
PL
3.44


Electron mobility
cm2/V s
Hall effect sensor
~150(300K)[1]

(1)Ammono S. A.
Hole mobility
cm2/V s
Hall effect sensor
13(300K)


Melting point
K
Thermal couple
2573


Lattice constants
nm
X-ray diffraction
a=0.319;c=0.518


Thermal conductivity(300K)
W/cm K
Time-domain thermoreflectance
2.2-2.5


Heat capacity
J/mol K
Constant presure heating
35.3


Elastic modulus
GPa
Mechanical measurement
210


Dislocation density
/cm2
TEM and XRD
≤5 x 106


Sheet carrier density
/cm2
SIMS
N/A


Sheet resistance/Resistivity
ohm-cm

0.1-1(Undoped)


<0.01(N type)

>106(Semi insulating)

Doping concentration
/cm3
SIMS
~1019(N type)[1]

(1)Ammono S. A.
N/A(P type)

Thickness
um
Ellipsometry
200-475(N type)


475(Semi insulating)

Misorientation
deg
SEM and TEM
On demand


Macro defect density
/cm2
TEM and XRD
A grade<=2; B grade>2


Bow
um
SEM or AFM
<5


Total thickness variation (TTV)
um
AFM(preferred) and SEM
<10


Surface roughness
nm
Profilometer and AFM
Ra<0.2;RMS<0.5(epi ready)


Thermal expansion coeff(300K)
/K
Thermal elastic measurement
along a0:5.59x10-6; along c0:7.75x10-6


Dielectric constant(300K)

Ellipsometry
along a0:10.4; along c0:9.5


Refractive index

Ellipsometry
2.67 at 3.38eV


Electron Effective mass


0.22


GaN template on sapphire Bandgap(300K)
eV
PL
3.44


Electron mobility
cm2/V s
Hall effect sensor
150(300K)*


Hole mobility
cm2/V s
Hall effect sensor
13(300K)*,20[1]

(1)MTI Corp.
Melting point
K
Thermal couple
2573


Lattice constants
nm
X-ray diffraction
a=0.319;c=0.518


Thermal conductivity(300K)
W/cm K
Time-domain thermoreflectance
2.3(semi insulating); 1.7(HVPE material,n=1x1017)


Heat capacity
J/mol K
Constant presure heating
35.3


Elastic modulus
GPa
Mechanical measurement
210


Dislocation density
/cm2
TEM and XRD
≤1 x 108[1,2,5]
5 x 108-6 x 108(for N type and undoped)[3]
8 x 108(for semi insulating)[3]
8 x 107-9 x 107(for N type and undoped)[4]

(1)Xiamen Powerway Advanced Material Co., Ltd.
(2)Anhui Haibei Import & Export Co., Ltd.
(3)Saint-Gobain Crystals-Photonic Materials
(4)Saint-Gobain Crystals-Photonic Materials
(5)Precision Micro-Optics LLC
Sheet carrier density
/cm2
SIMS
N/A


Sheet resistance/Resistivity
ohm-cm

<0.05(Undoped)[1]

(1)Xiamen Powerway Advanced Material Co., Ltd.
(2)Anhui Haibei Import & Export Co., Ltd.
(3)Precision Micro-Optics LLC
<0.05(N type)[1,2,3]

<1(P type)[1]

>106(Semi insulating)[1,2,3]

Doping concentration
/cm3
SIMS
~1019(N type)*
1x1018-3x1018(N type)[2]
3x1017(undoped)[2]

(1)Xiamen Powerway Advanced Material Co., Ltd.
(2)Saint-Gobain Crystals-Photonic Materials(3)MTI Corp.
~1017(P type)[1]
1017-3x1018(P type)[3]

Thickness(epilayer)
um
Ellipsometry
3-100(N type,undoped)[1,2,3,4]

(1)Xiamen Powerway Advanced Material Co., Ltd.
(2)Anhui Haibei Import & Export Co., Ltd.
(3)Saint-Gobain Crystals-Photonic Materials
(4)Precision Micro-Optics LLC
5-100(P type)[1]

20-90(Semi insulating)[1,2,3]

Buffer layer(sapphire) thickness
um
Ellipsometry
430[1],330[2]

(1)Xiamen Powerway Advanced Material Co., Ltd.
(2)Saint-Gobain Crystals-Photonic Materials
Misorientation
deg
SEM and TEM
On demand


Macro defect density
/cm2
TEM and XRD
<10


Bow
um
SEM or AFM
10-500


Total thickness variation (TTV)
um
AFM(prefered)and SEM
<10


Surface roughness
nm
Profilometer and AFM
Ra<0.2;RMS<0.5(epi ready)


Thermal expansion coeff(300K)
/K
Thermal elaastic measurement
along a0:5.59x10-6; along c0:7.75x10-6


Dielectric constant(300K)

Ellipsometry
along a0:10.4; along c0:9.5


Refractive index

Ellipsometry
2.67 at 3.38eV


Electron Effective mass


0.22


FWHM of(102)XRD arcsec

X-ray diffraction
<250[1], <300

(1)Xiamen Powerway Advanced Material Co., Ltd.
FWHM of(002)XRD arcsec

X-ray diffraction
<150[1]

(1)Xiamen Powerway Advanced Material Co., Ltd.
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